Mathematical modeling of the potentiodynamic and galvanostatic phase formation in melts

V.A. Isaev, O. V. Grishenkova, A. V. Kosov, O. L. Semerikova, Yu. P. Zaykov


The initial stages of the electrocrystallization process occurring in potentiodynamic and galvanostatic conditions were considered under a single scheme. It was shown that the proposed theoretical models are in a good agreement with the experimental results obtained at electrodeposition of silver crystals on the iridium microelectrode from nitrate melt containing an excess of supporting electrolyte.


 electrocrystallization, nucleation, growth, dissolution, cyclic voltammetry, galvanostatic method, diffusion, melt