Electroreduction of chromium (III) chloride and molybdenum (VI) oxide mixtures in a heat activated battery

O. V. Volkova, V. V. Zakharov

ABSTRACT

Discharge characteristics of a heat activated battery with CrCl3 –MoO3 mixtures as a cathode material is investigated. Composition and morphology of reduction products of the cathode materials have been determined. A mechanism of the reduction to metallic chromium and molibdenum has been proposed, which includes an intermediate step of melt formation of a Li3CrCl6 complex compound and lithium molybdates with LiCl.

KEY WORDS

Lithium heat activated battery, Cathode, Chromium chloride, Molybdenum oxide

Posted in electrochemistry, power sources.

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