Electrical conductivity and raman spectra of the α-Al2O3 – molten Li2CO3-Na2CO3-K2CO3-NaCl disperse systems

D. Zakiryanova, Е. V. Nikolaeva, А. L. Bove, B. D. Antonov.

ABSTRACT

Information on the specific electric conductivity of the dispersed system a-Al2O3-molten carbonate-chloride mixture of Li2CO3-Na2CO3-K2CO3-NaCl in the temperature range of 455–550 °C is obtained. Using the method of Raman spectroscopy, it was shown that in the investigated temperature range a-Al2O3 does not enter into a chemical interaction with the carbonate-chloride melt. Data on the strength and energy characteristics of the CO32– anion in these systems are obtained.

KEY WORDS

Conductivity, Raman spectra, disperse system, melts.

Posted in electrical conductivity, electrochemistry, molten salts, расплавы солей, электрохимия.

Leave a Reply

Your email address will not be published. Required fields are marked *