Corrosion of various types of stainless steels in chloraluminate melts

V. V. Karpov, A. V. Abramov, K. V. Dedov, A. V. Shak, A. Yu. Zhlyakov,

I. B. Polovov, S. V. Belikov, O. I. Rebrin

ABSTRACT

In the present work the corrosion behavior of 08Kh17T (analogue of AISI 439) ferritic steel, 12Kh13 (analogue of AISI 410) and 16Kh12MVSFBR ferritic-martensitic steels, and AISI 316L (analogue of 03Kh16N15M3), 12Kh18N10T (analogue of AISI 321) and 06KhN28MDT austenitic alloys was studied at 550°C in fused KCl–AlCl3 mixture with the initial AlCl3EtoEKCl ratio of 1.1. The corrosion rates of the studied materials in the KCl–AlCl3 were determined. The corrosion processes in all the studied iron-based steels were caused by the red-ox reactions resulting in dissolution of the most electronegative alloy components (Cr, Fe and Mn), that indicate the electrochemical nature of corrosion phenomena.

KEYWORDS

corrosion, stainless steel, chloraluminate melts, intergranular corrosion, molten salt reactor

DOI: 10.7868/S0235010619010067

Posted in corrosion, molten salts, nuclear industry, pyrochemical technology, расплавы солей.

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