Selective anode dissolution of gold alloys in a molten eutectic mixture of cesium, potassium, sodium chlorides

L. V. Sitnikov, N. P. Kulik, N. K. Tkachev, A. A. Pankratov, V. B. Malkov, V. M. Ivenko, N. G. Molchanova, N. I. Moskalenko, B. D. Antonov

ABSTRACT

The features of selective anodic dissolution of Al11Au6 intermetallide and Au–Cu–Ag solid solution in the melt of CsCl–KCl–NaCl eutectic at 520оС were studied. Microporous structures containing up to 95 mol % of gold were fabricated in the potentiostatic regime. It is shown that the pore size and distribution depend essentially on the nature of the alloy, and the mechanical strength of the sample during and after the dealloing is strongly influenced by the magnitude of the applied potential.

KEYWORDS:  

selective dissolution, gold alloys, anodic polarization, molten salts, porous structure

Posted in electrochemistry, molten salts, электрохимия.

Leave a Reply

Your email address will not be published. Required fields are marked *